基于柱[n]芳烃(准)轮烷的研究进展  

Recent Advances of (Pseudo) Rotaxanes Constructed by Pillar[n]arenes

作　　者：吴旋[1] 段群鹏[1,2] 倪梦飞 胡晓玉[1] 王乐勇[1] 

机构地区：[1]超分子化学与智能材料实验室南京大学化学化工学院,南京210093 [2]河南工程学院材料与化学工程系,郑州450007

出　　处：《有机化学》2014年第3期437-449,共13页Chinese Journal of Organic Chemistry

基　　金：国家自然科学基金(No.21202083);江苏省自然科学基金(No.BK2011055)资助项目~~

摘　　要：柱芳烃作为一类新型的大环主体分子,自2008年首次报道以来,引起了人们,特别是化学家的广泛关注.目前,它已在分子识别、(准)轮烷、超分子聚合物、分子弹簧、智能跨膜离子通道、囊泡、金属有机骨架结构等众多研究领域作为重要模块得到初步的应用.主要将以柱芳烃作为主体大环分子来构筑(准)轮烷的研究进展进行简要的综述,同时还介绍了基于柱芳烃的(准)聚轮烷的研究概况,并对未来的发展作了进一步展望.Pillar[n]arenes, as a new generation of macrocyclic host molecules, have attracted widely attention since their dis- covery in 2008. They have been applied in the field of molecule recognition, rotaxanes, supramolecular polymers, molecular springs, artificial transmembrane channels, vesicles, and metal-organic frameworks （MOFs）. In this review, the recent ad- vances of （pseudo）rotaxanes constructed by pillar[n]arenes are reviewed. Meanwhile, the advances of poly（pseudo）rotaxanes based on pillar[n]arenes are also briefly summarized.

关 键 词：柱[n]芳烃 (准)轮烷 (准)聚轮烷 

分 类 号：O641.3[理学—物理化学]