芳香整理织物中丁香酚的GC/MS测定法  

Determination of eugenol in fragrant fabrics by GC /MS method

作　　者：顾娟红[1] 潘葵[1] 柳艳[1] 朱振华[1] 

机构地区：[1]苏州出入境检验检疫局综合技术中心,江苏苏州215104

出　　处：《印染》2014年第7期40-41,45,共3页China Dyeing and Finishing

基　　金：国家质检总局科技计划项目(2013IK109)

摘　　要：建立了芳香整理织物中丁香酚的气相色谱-质谱（GC／MS）分析方法。样品经甲醇超声萃取、浓缩、定容后，用DB-5MS柱分离，选择离子（SIM）模式下定量检测。在优化的试验条件下，线性范围为0．01～100μg／mL，相关系数为0．9991，定量下限为0．03mg／kg，加标回收率在89．7％～92．3％，相对标准偏差小于4．7％。该方法灵敏度高、操作简单，可用于芳香织物中芳香剂丁香酚含量的快速检测。A method is developed for the determination of eugenol in fragrant fabrics by gas chromatography-mass spectrometry （GC-MS）. Textiles are ultrasonically extracted with methanol as an extractor. The extraction solution is concentrated and blown dry, and then redissolved in extraction solvent. The separation is done on an HP-SMS column, and determination is carried out with selected ion monitoring（ SIM ）, Under the optimum conditions, the calibration curves are linear in the range of 0.01- 100 μg/mL with correlation coefficient of 0.999 1. The method detection limit is 0.03 mg/kg. The spiked recoveries are between 89.7%-92.3% with the relative standard deviation no more than 4.7%. The proposed method is sensitive and rapid, and is suitable for the determination of eugenol in fragrant fabrics.

关 键 词：测试 气相色谱法 质谱法 芳香织物 丁香酚 

分 类 号：TS107[轻工技术与工程—纺织工程]