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机构地区:[1]华南理工大学化学与化工学院,广东广州510641
出 处:《广东化工》2014年第7期91-92,共2页Guangdong Chemical Industry
摘 要:金属有机骨架材料(MOFs)作为近十年来新兴的配位化合物,具有有序的孔道结构、大比表面积、高的空隙率和,其结构和性质可调性,可应用于气体储存和分离、催化等方面。但是由于MOFs相对较差的稳定性,其大规模工业应用受到限制。目前,研究们试图将其这一缺点利用起来,如将MOFs进行烧结,将裂解后的材料用于气体吸附、电化学催化、锂电池、传感器、燃料电池中的氧气还原反应等等方面。本文对烧结MOFs制备多孔材料及其应用进行了归纳总结。The metal-organic framework materials (MOFs) as emerging coordination compounds over the past decade, has ordered pore structure, large surface area, high porosity and its structure and properties adjustable, can be applied to gas storage separation, catalysis and so on. However, due to the relatively poor stability, its large-scale industrial application is limited. Currently, researcher have attempted to utilize this drawback, sintering synthesis MOF-derived nanoporous material for gas adsorption, the electrochemical catalysis, lithium batteries, sensors, fuel cells, the oxygen reduction reaction etc. Prepared for the MOF-derived nanoporous material and their applications were summarized.
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