Synthesis, Structure and Norbornene Polymerization Catalyzed by o-Benzene Diimine Di-nuclear Palladium(Ⅱ) Complex  

作　　者：李超 兰梅英 孟素芹 陈建新 张治纯 

机构地区：[1]College of Chemistry and Chemical Engineering,Fujian Normal University [2]State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences

出　　处：《Chinese Journal of Structural Chemistry》2014年第4期607-611,共5页结构化学（英文）

基　　金：supported by the Natural Science Foundation of Fujian Province(2010J01026);the Ministry of Education of China(No.208066);the Education Department of Fujian Province(JA07029);the State Key Laboratory of Structural Chemistry(No.20130013)

摘　　要：The title complex, C20H17N4Pd2Cl3·0.5CH3OH, crystallizes in the triclinic system, space group Pī with α = 9.927（6）, b = 11.079（6）, c = 11.233（6） ？, a = 73.970（12）, β = 85.738（16）, γ = 83.300（12）o, V = 1178.1（11） ？3, Mr = 648.55, Z = 2, Dc = 1.520 g/cm3, μ = 1.884 mm-1, F（000） = 634, the final R = 0.0460 and wR = 0.1280. This title compound was investigated for the catalytic behavior towards norbornene （NB） vinyl addition polymerization. And the complex exhibits good catalytic activity to catalyze norbornene polymerization using MAO as a cocatalyst.The title complex, C20H17N4Pd2Cl3·0.5CH3OH, crystallizes in the triclinic system, space group Pī with α = 9.927（6）, b = 11.079（6）, c = 11.233（6） ？, a = 73.970（12）, β = 85.738（16）, γ = 83.300（12）o, V = 1178.1（11） ？3, Mr = 648.55, Z = 2, Dc = 1.520 g/cm3, μ = 1.884 mm-1, F（000） = 634, the final R = 0.0460 and wR = 0.1280. This title compound was investigated for the catalytic behavior towards norbornene （NB） vinyl addition polymerization. And the complex exhibits good catalytic activity to catalyze norbornene polymerization using MAO as a cocatalyst.

关 键 词：palladium complex catalyst crystal structure norbornene polymerization 

分 类 号：O643.36[理学—物理化学] TQ231.2[理学—化学]