The Impact of Nickel Source/Doping Elements/Buffer on the Structure of Ni(OH)_2  

作　　者：许庆胜 朱燕娟 HAN Quanyong LUO Jie MIAO Chengcheng ZHANG Wei ZHANG Chunhua 

机构地区：[1]School of Physics and Optoelectronic Engineering, Guangdong University of Technology

出　　处：《Journal of Wuhan University of Technology(Materials Science)》2014年第1期44-48,共5页武汉理工大学学报（材料科学英文版）

基　　金：Funded by the National Natural Science Foundation of China(No.11304045);the Guangdong Province National Natural Science Foundation of China(No.S2012010009955);the Science and Technology Program of Guangzhou City of China(No.2013j4100011)

摘　　要：The nano-nickel hydroxide samples were prepared by means of ultrasonic-assisted precipitation and the impact of source/doping element/buffer on the structure of Ni（OH）： was studied. The results of XRD, IR and TEM testing clearly revealed that larger anionic radius of the nickel sources or the buffer solution was conducive to the formation of α-Ni（OH）2. The proportion of α-Ni（OH）： samples doped with two elements was larger than that doped with single element. Additionally, speciation, valence as well as the radius of doping ions can directly affect the phase of Ni（OH）2.The nano-nickel hydroxide samples were prepared by means of ultrasonic-assisted precipitation and the impact of source/doping element/buffer on the structure of Ni（OH）： was studied. The results of XRD, IR and TEM testing clearly revealed that larger anionic radius of the nickel sources or the buffer solution was conducive to the formation of α-Ni（OH）2. The proportion of α-Ni（OH）： samples doped with two elements was larger than that doped with single element. Additionally, speciation, valence as well as the radius of doping ions can directly affect the phase of Ni（OH）2.

关 键 词：multiphase nano-Ni（OH）： ultrasonic-assisted precipitation Y/Cu-doped FTIR XRD TEM 

分 类 号：O614.813[理学—无机化学]