NaOH亚熔盐法分解钾长石矿  

Decomposition of Potassium Feldspar by NaOH Sub-molten Salt Method

作　　者：王颖[1] 郭菊花[1,2] 黄金凤[1,2] 陈华丹 关怀民[3] 曹吉林[4] 童跃进[1,2] 

机构地区：[1]福建师范大学化学与化工学院,福建福州350007 [2]福建师范大学化工新材料研究所,福建福州350007 [3]福建师范大学材料科学与工程学院,福建福州350007 [4]河北工业大学化工学院,天津300130

出　　处：《过程工程学报》2014年第2期280-285,共6页The Chinese Journal of Process Engineering

基　　金：福建省科技厅高校产学研重大项目资助(编号:2013H6006);福建省教育厅B类项目资助(编号:JB12047)

摘　　要：以高浓度NaOH溶液为亚熔盐介质分解钾长石矿精粉,考察了矿物粒径、NaOH溶液浓度、搅拌速度、反应时间、反应温度、液固比对K+溶出率的影响,并对分解过程动力学进行分析.结果表明,100μm粒径钾长石矿精粉的最佳反应条件为:NaOH初始浓度60%(ω)、反应温度约160℃、搅拌速度400 r/min、液固质量比4:1、反应140 min,该条件下K+溶出率大于98%.钾长石的分解符合粒径恒定的缩核模型,反应初期固相产物层内扩散为速控步骤.80～140℃下,反应的表观活化能为110.42 kJ/mol.High concentration NaOH sub-molten salt was used to decompose potassium feldspar powder. The effects of the particle size, concentration of NaOH, stirring speed, reaction time, reaction temperature and mass ratio of liquid to solid on the dissolution rate of K^＋ were studied. The optimum reaction conditions were obtained for 100 lain diameter potassium feldspar powder, that is, NaOH initial concentration 60%（co）, reaction temperature about 160℃, stirring speed 400 r/rain, and mass ratio of liquid to solid 4：1. After 140 min reaction, the dissolution rate of K^＋ was over 98%（ω）. The decomposition kinetics of potassium feldspar powder under the reaction conditions was studied. The decomposition rate of potassium feldspar powder was in accordance with the shrinking core model at constant particle size. The reaction was controlled by the internal diffusion through ash layer in the initial stage of reaction. The kinetic constants were estimated, and the apparent activation energy was 110.42 k J/tool at the temperatures of 80-140 ℃.

关 键 词：钾长石 亚熔盐 NAOH 钾离子 溶出 分解 

分 类 号：TQ442[化学工程—化学肥料工业]