Leaching kinetics of selenium from selenium-tellurium-rich materials in sodium sulfite solutions  

Na_2SO_3从硒碲富集物中浸出硒动力学(英文)

作　　者：郑雅杰[1] 陈昆昆[2] 

机构地区：[1]中南大学冶金与环境学院,长沙410083 [2]西北有色金属研究院电子材料研究所,西安710016

出　　处：《Transactions of Nonferrous Metals Society of China》2014年第2期536-543,共8页中国有色金属学报（英文版）

基　　金：Project(2011B0508000033)supported by the Special Foundation of Guangdong Province Major Science&Technology Program of China

摘　　要：The leaching kinetics of selenium from selenium-tellurium-rich materials in sodium sulfite solutions was studied. The morphologies of selenium-tellurium-rich materials are mainly spheroid and columnar bodies and the range of particle size of selenium-tellurium-rich materials is between 17.77μm and 56.58μm, which contain 41.73%selenium and 40.96%tellurium. The ranges of experimental elements are 126-315 g/L of sodium sulfite concentration, 100-400 r/min of agitation speed, 23-95 ℃ of reaction temperature, 7：1-14：1 of liquid-solid ratio and 17.77-56.58μm of average particle size. The results show that the leaching rate increases with increasing the sodium sulfite concentration, agitation speed, reaction temperature or liquid-solid ratio and the leaching rate decreases with increasing the particle size. The reaction temperature has the significant effects on the selenium leaching rate which increases from 21%to 67%with increasing temperature from 23 ℃ to 95 ℃. The experimental data agree quite well with the Avrami model for leaching, with model parameter of 0.235 and apparent activation energy of 20.847 kJ/mol.研究用Na2SO3溶液从硒碲富集物中浸出硒的动力学。该硒碲富集物的微观形貌主要为球状体和柱状体,其粒径范围为17.77～56.58μm,且其主要成分为41.73%Se和40.96%Te。研究Na2SO3浓度(126～315 g/L)、搅拌速度(100～400 r/min)、反应温度(23～95°C)、液固比(7:1～14:1)及硒碲富集物平均粒径(17.77～56.58μm)对Se浸出率的影响。结果表明:增加Na2SO3浓度、提高搅拌速度、升高反应温度和增加液固比均可以提高Se浸出率,而增大硒碲富集物的粒径会导致Se的浸出率降低;反应温度对Se浸出率影响较大,当反应温度从23°C升高至95°C时,Se浸出率从21%增至67%;该浸出过程符合Avrami模型,其模型特征参数和表观活化能分别为0.235和20.847kJ/mol。

关 键 词：SELENIUM TELLURIUM sodium sulfite leaching kinetics 

分 类 号：TD95[矿业工程—选矿]