以戊二醛为活性基团的蒽醌型活性染料XB2的合成与应用  

Synthesis and Application of Anthraquinone Reactive Dye XB2 with Glutaraldehyde as Reactive Group

作　　者：陈效[1] 丁克毅[1] 刘军[1] 

机构地区：[1]西南民族大学化学与环境保护工程学院,四川成都610041

出　　处：《中国皮革》2014年第9期5-8,15,共5页China Leather

基　　金：国家自然科学基金项目"天然环烯醚萜及其类似合成产物的交联呈色机理和构效关系研究"(项目编号:21176202);西南民族大学研究生创新科研一般项目"一种新型蒽醌活性染料的制备"(CX2013SP01)

摘　　要：利用溴氨酸钠与间苯二胺进行芳胺化反应，再与溴代物缩合、水解，得到以戊二醛为活性基团的蒽醌型活性染料XB2。对芳胺化反应（获取色基1）的工艺参数进行了筛选和优化，适宜条件为：pH=9，SnCl：／CuSO。（n：n）=2：1，间苯二胺／溴氨酸钠（n：n）=1．5：1，色基1的收率为90％；通过紫外、红外和质谱对目标产物XB2进行了结构表征。用XB2对浸酸羊皮进行鞣制和染色试验的结果表明：当XB2用量达到浸酸羊皮质量的3％时，皮块的收缩温度达到72．5℃，皮块同时被染成蓝黑色；水洗牢度测试的结果表明，XB2的耐水洗牢度达到4～5级。Anthraquinone reactive dye XB2 with glutaraldehyde as reactive group was obtained by the following procedure ： aromatic amination reaction happened between benzene -1,3 -diamine and 1 -amino- 4 -bromoanthraquinone- 2 -sulfonic acid sodium, then the intermediate - 1 product was condensed with another bromide compound to get pre - dye. The pre - dye was hy- drolyzed to produce the target product XB2. The best reaction conditions of aromatic amination reaction are as follows： pH = 9, SnCl2/CuSO4（n：n） =2：1, benzene -1, 3- diamine/ 1- amino - 4- bromoanthraquinone - 2- sulfonic acid sodium（n： n） = 1.5：1. At this condition, the yield of intermediate - 1 is 90%. UV - vis, FTIR and HPLC - MS are applied to identify the target product XB2. The target product is also applied to tanning and dyeing in pickled goat pelt. The shrinkage temperature （Ts） of leather is 72.5℃ when the dosage of XB2 is 3% （w/w） and the pelt is dyed dark blue. The result of water -washing experiment indicates that XB2 has a good washing fastness, which is grade 4 - 5.

关 键 词：戊二醛 蒽醌染料 活性染料 鞣剂 

分 类 号：TQ613.2[化学工程—精细化工]