十八烷膨胀珍珠岩定形相变材料封装及隔热性能  

Heat-insulating property and encapsulation of octadecane expanded perlite shape-stabilized phase change materials

作　　者：王伟[1,2] 严捍东[2] 

机构地区：[1]华侨大学材料科学与工程学院,福建厦门361021 [2]华侨大学土木工程学院,福建厦门361021

出　　处：《化工进展》2014年第5期1242-1246,1295,共6页Chemical Industry and Engineering Progress

基　　金：国家自然科学基金(51078156);福建省重大专项(2008HZ003-1)项目

摘　　要：以十八烷为相变材料,膨胀珍珠岩为支撑材料,采用浸泡吸附工艺制备定形相变材料。通过DSC、FT-IR、ESEM等测试技术对相变材料及定形相变材料进行表征。为减少在水泥基质中使用时相变材料融化泄漏,本文尝试采用湿裹水泥干粉工艺对该定形相变材料进行表面封装,在60℃下连续烘烤20h,封装前后十八烷在膨胀珍珠岩中的容留率由75%提高到97%以上。隔热性能测试结果表明:以封装后的定形相变材料等质量取代水泥砂浆中40%砂,与基准砂浆板相比,10mm和15mm厚度砂浆板下表面时间延迟和最大温差分别为230s、4.2℃和500s、6.2℃。经历25次冷热循环的相变砂浆,15mm厚度砂浆板下表面时间延迟仍有360s,最大温差4.3℃。A kind of shape-stabilized phase change materials（SPCMs） was prepared by soaking absorbing technology with octadecane as phase change materials（PCMs） and expanded perlite as supportive material. The PCMs and SPCMs were characterized by DSC,FT-IR and ESEM. The surface of the SPCMs were packaged tentatively by the technology of wet-wrapping cement dry powder in order to reduce the possibility of melting leakage of PCMs in the cement matrix. The holding ratio of the octadecane absorbed in expanded perlite increased from 75 percent to above 97 percent after surface packaging SPCMs which were baked under 60℃ for continuous 20 hours. The heat-insulating property experiment results show that the lower surface time delay and the maximum temperature difference are 230 s,4.2℃ and 500s,6.2℃ respectively for 10mm thickness and 15mm thickness mortar board with 40 percent by weight of sand in the reference mortar mixture replaced by packaged SPCMs,compared to those of same thickness reference mortar board the form-stable phase change materials wrapped by cement,baked for 20 hours under 60℃,and absorption rate changes from 75%to 97% after packing. The lower surface time delay and the maximum temperature difference of 15mm thickness phase change mortar board still have 360s and 4.3℃ after experiencing 25 thermocycling.

关 键 词：多孔介质 烷烃 相变材料 定形相变材料 相变砂浆 热力学性质 

分 类 号：TU55[建筑科学—建筑技术科学]