对称席夫碱锌卟啉化合物的合成及性能研究  

Synthesis and Properties of Symmetric Schiff Base Zinc Porphyrins

作　　者：朱英[1] 张学俊[1] 武晓博[1] 

机构地区：[1]中北大学理学院,山西太原030051

出　　处：《化学试剂》2014年第5期397-400,共4页Chemical Reagents

基　　金：山西省自然科学基金资助项目(2011011022-4)

摘　　要：以乳酸、对硝基苯甲醛和吡咯为主要原料,硝基苯为溶剂合成meso-四(4-硝基)苯基卟啉化合物,通过浓盐酸和氯化亚锡还原得到对应的氨基卟啉,与锌配位后,在四氢呋喃为溶剂,冰醋酸为催化剂的作用下,与3种醛反应合成3种标题化合物。利用核磁共振氢谱,IR,UV-Vis,荧光,循环伏安法等方法确定了目标化合物的结构、光谱特征和电化学性能。讨论了不同给电子基团的引入对光谱性能及氧化还原能力的影响。Meso-tetra （4-nitro） phenyl porphyrins were synthe- sized by 4-nitrobenzene formaldehyde and pyrrole in nitroben- zene,which lactic acid was as catalyst,then were reduced to Meso-tetra（4-amino） phenyl porphyfins by using SnC12 and HCl. Three symmetrical Schiff base zinc porphyrins were ob- tained by meso-tetra （ 4-amino ） phenyl zinc porphyrins reac- tion with three kinds of aldehyde, respectively. The structures and optlcal,eleetrochemieal properties of porphyfins were de- termined by 1 HNMR, IR, UV-Vis, fluorescence cyclic voltam- metry. The influence of the different electronic groups on spectral properties and the redox ability was discussed.

关 键 词：锌卟啉 席夫碱 合成 电化学 

分 类 号：O621.2[理学—有机化学]