氯代聚并苯同系分子的能量和电子极化率与同系序数的相关性研究  

Studies on Connectivity Between The Energy And Electronic Polavizabilities Of Chloro Polyacence And Its Homologus Number

作　　者：欧阳礼[1] 李良超[2] 

机构地区：[1]桂林市教育学院化学系,广西桂林541001 [2]荆州师范学院化学系,湖北荆州434100

出　　处：《桂林市教育学院学报》2000年第1期95-99,共5页

摘　　要：氯代聚并苯同系物的能量和电子极化率与同系序数之间满足下列相关方程E=a Nβ+b,　　　　　　　　　R≈ lα(或 απ ) =α′ Nβ′+b′,R≥ 0 .9990απ/ α(% ) =α″Nβ″+b″,R≥ 0 .9999N=2 n+1,为同系序数 ,n为苯环的结构单元数 β、β′、β″随同系分子的类型而变 。WT5BZ]set correlation equation was contented with energy and electronic polarizability of chloro polyacence homologue and its homologous number. E = a N β+ b, R≈l α(或α π )=α′ N β′ + b′, R≥0.9990 α π/α(%)=α″ N β″ +b″, R≥0.9999 where,N=2n+1,are homologus number,n is structural unit numbers of benzene ring,β、 β′ and β″ are Varing with series of homologue,The calculated Values are well agree with literature ones.

关 键 词：氯代聚并苯 能量 电子极化率 同系序数 同系物 

分 类 号：O632.7[理学—高分子化学]