差压热耦合反应精馏应用于乙酸甲酯水解研究  

Simulation study of different pressure thermally coupled reactive distillation column for hydrolysis of methyl acetate

作　　者：李军[1,2] 王汝军 王丁丁 马占华 孙兰义 

机构地区：[1]中国海洋大学化学化工学院,山东青岛266100 [2]中国石油大学重质油国家重点实验室,山东青岛266580

出　　处：《中国石油大学学报（自然科学版）》2014年第1期155-160,共6页Journal of China University of Petroleum(Edition of Natural Science)

基　　金：国家自然科学基金(21276279);中央高校基本科研业务费专项(12CX04026A)

摘　　要：结合差压热耦合和反应精馏工艺优势,提出形成差压热耦合反应的精馏工艺方法,将其应用于乙酸甲酯水解过程。在验证UNIQ-HOC模型对模拟该体系适用性的基础上,对影响该工艺的主要影响因素进行考察,得出优化后的主要操作参数,并对比差压热耦合精馏和常规流程的能耗。结果表明,差压热耦合反应精馏增加813.33 kW的功耗,减少7062.3 kW的热量,节能效果显著。A different pressure thermally coupled reactive distillation column was proposed for the methyl acetate hydrolysisprocess by combining differential thermal coupled distillation with reactive distillation. It was verified that UNIQ-HOC modelcan be successfully applied to VLE prediction of this system. The main parameters affecting the process were investigated andthe optimized operating parameters were obtained. The results show that the different pressure thermally coupled reactive dis-tillation process can save about 89% of energy compared with the conventional process.

关 键 词：乙酸甲酯水解 差压热耦合 反应精馏 模拟优化 节能 

分 类 号：TQ028[化学工程]