6-偕二硝基乙烯基-4,5,8-三硝基-5,6,7,8-四氢化-4H-咪唑烷并[4,5-e]呋咱并[3,4-b]哌嗪的合成(英文)  

Synthesis of 6-Dinitroethylene-4,5,8-trinitro-5,6,7,8-tetrahydro-4H-imidazo[4,5-e] furazano [3,4-b] piperazine

作　　者：霍欢[1] 王伯周[1] 廉鹏[1] 来蔚鹏[1] 李辉[1] 葛忠学[1] 

机构地区：[1]西安近代化学研究所,陕西西安710065

出　　处：《含能材料》2014年第2期274-275,共2页Chinese Journal of Energetic Materials

基　　金：Foundation Research Project of National Defence(B0920110051)

摘　　要：以FOX-7和乙二醛为原料,经过两步缩合环化反应和硝化反应,首次设计并合成出了一种新型的呋咱稠环硝胺化合物6-偕二硝基乙烯基-4,5,8-三硝基-5,6,7,8-四氢化-4H-咪唑烷并[4,5-e]呋咱并[3,4-b]哌嗪(PNEIFP)。采用Gaussian 09程序和VLW方程计算PNEIFP的密度、生成焓和爆速分别为2.02 g·cm-3、724.1 kJ·mol-1和9681.0 m·s-1。利用TLC跟踪实验的方法,确定PNEIFP室温下易分解。A novel energetic compound,6-dinitroethylene-4,5,8-trinitro-5,6,7,8-tetrahydro-4H-imidazo [4,5-e] furazano [3,4-b] piperazine（ PN EIFP）,w as designed and synthesized from glyoxal and FO X-7 by tw o cyclizations and nitration. In addition,some properties of PN EIFP w ere calculated by Gaussian 09program and VLW formula. T he results show that its density is 2. 02 g·cm^-3,and the detonation velocity is9681.0 m·s^-1,and the enthalpy of formation is724. 1 kJ·mol^-1. PN EIFP easily decomposes at room temperature.

关 键 词：有机化学 合成 6-偕二硝基乙烯基-4 5 8-三硝基-5 6 7 8-四氢化-4H-咪唑烷并[4 5-e]呋咱并[3 4-b]哌嗪 性能 

分 类 号：TQ560.1[化学工程—炸药化工]