Au/L-Met/GC电极的H_2O_2电催化氧化  

Electro-Catalytic Oxidation of Hydrogen Peroxide on Au/L-Methionine/GC Electrode

作　　者：范建凤[1] 罗雪梅[1] 李婧[1] 范楼珍[2] 

机构地区：[1]忻州师范学院化学系,山西忻州034000 [2]北京师范大学化学学院,北京100875

出　　处：《电化学》2014年第2期146-149,共4页Journal of Electrochemistry

基　　金：国家自然科学基金项目(No.21073018);山西省高等学校科技创新项目(No.20121023);忻州师范学院化学化工创新实践基地项目资助

摘　　要：在无额外的添加剂和保护剂的情况下，以柠檬酸钠还原氯金酸制得链状金纳米粒子，使用扫描电子显微镜（SEM）和透射电子显微镜（TEM）观察样品．层层自组装技术可将金纳米粒子自组装，并分别以L一甲硫氨酸（L-Methionine，L-Met）、硫脲（Thiourea，TU）、丙烯基硫脲（Allyl thiourea，ATU）和聚乙烯吡咯烷酮（Polyvinyrrolidone，PVP）交联剂自组装于玻碳基底，即得金纳米粒子修饰电极．以[Fe（CN）6]3-/4-氧化还原电对为探针，考察该修饰电极的电化学性质．Au／L—Met／GC电极有最佳电化学性能，循环伏安曲线和计时电流曲线测试表明，Au几．Met／GC电极的H202电催化氧化有较高的灵敏度，线性范围2x10-7～3×10-3mol·L-1，检出限6．67×10 -8mol·L-1．The modified electrodes have been fabricated by generation of Au nanoparticle chains, which was produced by reaction between HAuC14 and sodium citrate without any additional capping agents or surfactants. The self-assembled Au nanoparticles were attached to the surface of glassy carbon electrode （GCE） layer by layer, using L-methionine （L-Met）, thiourea （TU）, allyl thiourea （ATU） and polyvinylpyrrolidone （PVP） as a crosslinking agent, respectively. The experimental results showed that the electrochemical performance of the different modified electrodes varied in [Fe（CN）6]34. solution. The Au/L-Met/GCE exhibited an excellent electrochemical property, which is superior to other modified electrodes. In addition, the catalysis of Au/L-Met/GCE to hydrogen peroxide （H202） also performed a good sensitivity to electrochemical oxidation of H202 during cyclic voltammetry and chronoamperometry analyses. And the linear range and detection limit for H202 were 2 × 10.7 - 3 × 10-3 mol. L-1 and 6.67x 108 mol. L-1, respectively.

关 键 词：金纳米粒子链 交联剂 电化学 催化氧化 

分 类 号：O646[理学—物理化学]