三重和四重氢键体系:设计、结构和应用  

Triply and Quadruply Hydrogen Bonded Systems: Design,Structure and Application

作　　者：杨勇[1] 窦丹丹[1] 

机构地区：[1]浙江理工大学,杭州310018

出　　处：《化学进展》2014年第5期706-726,共21页Progress in Chemistry

基　　金：国家自然科学基金项目(No.91227105);浙江省自然科学基金项目(No.LY12B02021);教育部留学回国人员科研启动基金;浙江理工大学"应用化学与生态染整工程"浙江省高校重中之重学科优秀青年人才培养基金(No.ZYG2011001);"521人才培养计划"资助~~

摘　　要：氢键是超分子化学领域具有特别重要地位的一种非共价作用。近年来,通过氢键自组装制备超分子聚合物已经成为超分子化学的一个热门研究领域。构筑性能优良的多重氢键体系奠定了这个领域的研究基础。其中,三重和四重氢键体系在构筑超分子组装体方面得到了广泛应用。本文综述了三重氢键、四重氢键组装体系的研究进展及其应用,重点介绍了各种三重氢键、四重氢键体系的设计思路和影响其稳定性的各种因素。Hydrogen bonding is a kind of noncovalent interaction that holds a very important position in the field of supramolecular chemistry. In the past few years,hydrogen bonding mediated supramolecular polymer has become a hot research topic in supramolecular chemistry. The construction of excellent hydrogen bonding building blocks lies the basis for the area. Among that,triply and quadruply hydrogen bonded systems are w idely used for the construction of supramolecular assemblies. In this article, w e summarize the progress and applications of triply and quadruply hydrogen bonded systems. We put our emphasis on the design principles of such systems and the factors affecting the stability of each system.

关 键 词：氢键 三重氢键体系 四重氢键体系 超分子聚合物 超分子化学 

分 类 号：O641.3[理学—物理化学]