水玻璃相中制备纳米CdS及结构表征  

A Study of Nanocrystalline CdS Prepared in Waterglass Medium

作　　者：刘孝恒[1] 梁春香[1] 李丹[1] 杨绪杰[1] 陆路德[1] 汪信[1] 

机构地区：[1]南京理工大学材料化学实验室,南京210094

出　　处：《北京大学学报（自然科学版）》2001年第2期231-234,共4页Acta Scientiarum Naturalium Universitatis Pekinensis

基　　金：教育部博士点基金 !(1999 2 0 0 1)资助项目

摘　　要：室温下将Cd(NO3) 2 溶液滴加至水玻璃与Na2 S混合溶液中 ,搅拌 6h后经处理得CdS细粉。XRD检测表明它们的主要晶型趋于立方ZnS型 ,平均粒径为 1 4～ 3 7nm ,其颗粒尺寸受水玻璃浓度的控制 ;TEM检测显示CdS结晶颗粒包裹有非晶态CdS ,其CdS粉体呈较好的分散性 ;光谱分析结果表明所制备纳米CdS的能隙约为 3 1eV 。At room temperature,Cd(NO 3) 2 solution was dropped in the quickly stirred aqueous solution consisted of Na 2S and waterglass.After the mixture was stirred for 6h,the powders of nanocrystalline CdS were obtained by careful washing and filtering,which were characterized by XRD,TEM and absorption spectrometer.It was found that the average particle diameter(1 4～3 7?nm) of CdS powders is controlled by waterglass concentrations,prevailing crystal system whose particles were wrapped by non\|crystal CdS belongs to wurtzite phase and the related optical band gap reaches 3.1?eV.It was assumed that the non\|crystal CdS wrapped on crystal CdS can result in red\|shifted luminescence for absorption spectrum.

关 键 词：平均粒径 能隙 吸收光谱 半导体纳米粒子 硫化镉 结构表征 水玻璃相 晶型 

分 类 号：O614[理学—无机化学]