Progress of transition metal-catalyzed cross-coupling mediated by PyBroP  

作　　者：Guojun Chen Jianshi Du 

机构地区：[1]College of Science,Changchun Institute of Technology [2]Vascular Surgery,The Third Hospital of Jilin University

出　　处：《Chinese Science Bulletin》2014年第17期1942-1949,共8页

基　　金：supported by the Public Welfare Technology Applied Project of Lishui City (2012JYZB32)

摘　　要：In the transition metal-catalyzed cross-coupling reactions,phenol and enol derivatives activated by phosphorus groups are very important electrophiles.This kind of compounds has the advantages of easy preparation,great stability,and producing more benign phosphorus by-products.The present work provides a comprehensive review of the advances made over the past several decades in this area.Cross-coupling reactions mediated by PyBroP are first surveyed,then two types of recently developed transition metal-catalyzed reactions,i.e.,Pd-catalyzed and Nicatalyzed reactions,and the corresponding mechanisms are discussed.Finally,future directions are analyzed.In the transition metal-catalyzed cross-coupling reactions, phenol and enol derivatives activated by phos- phorus groups are very important electrophiles. This kind of compounds has the advantages of easy preparation, great stability, and producing more benign phosphorus by-pro- ducts. The present work provides a comprehensive review of the advances made over the past several decades in this area. Cross-coupling reactions mediated by PyBroP are first surveyed, then two types of recently developed tran- sition metal-catalyzed reactions, i.e., Pd-catalyzed and Ni- catalyzed reactions, and the corresponding mechanisms are discussed. Finally, future directions are analyzed.

关 键 词：过渡金属催化 介导 交叉偶联反应 联通 亲电试剂 催化反应 衍生物 化合物 

分 类 号：O621.25[理学—有机化学]