手性负载型salen催化剂的研究进展  

Progressing on supported chiral salen catalysts

作　　者：王进[1] 母佳利[1] 陕绍云[1] 伍水生[1] 苏红莹[1] 贾庆明[1] 

机构地区：[1]昆明理工大学化学工程学院,昆明650500

出　　处：《功能材料》2014年第B06期20-24,共5页Journal of Functional Materials

基　　金：国家自然科学基金资助项目(21366014;51364023;31160146;51104075);云南省中青年学术技术带头人后备人才资助项目(2009CI029)

摘　　要：手性salen化合物是近几年发展起来的用于不对称催化反应的高效催化剂,自合成以来一直受到人们的关注。目前均相手性salen研究已相对成熟,但距离实现进一步的工业化还有很大差距。手性salen化合物的固载化可望实现手性salen的工业化应用,已成为本领域的研究热点。从无机载体、有机载体和近几年发展起来的有机-无机复合载体3个方面综述了固载手性salen化合物的不同方法及研究进展,并做了分析比较。Since chiral salen compounds were synthesized,they developed rapidly.Chiral salen compounds were widely used as catalysis for asymmetric reactions,but it was difficult to achieve industrial production.The im-mobilization of chiral salen compounds was found to be more effective to be applied to industrial production,and it attracted more and more attention.This review summarized different strategies and development to immobi-lize chiral salen compounds,going from organic supports,inorganic supports and new types of organic-inorganic hybrid material supports.The analysis and comparison of supported chiral salen compounds were also presented.

关 键 词：手性SALEN 固载 不对称催化 进展 

分 类 号：O621[理学—有机化学]