锡粉促进下由醛、芳甲酰肼和烯丙基溴“一锅法”合成高烯丙基酰肼化合物  

Tin-Mediated “One-Pot” Synthesis of Homoallylhydrazides from Aldehydes, Aryl Acylhydrazines and Allyl Bromide

作　　者：陆爱玲[1] 王凤娇[1] 黄丹凤[1] 王克虎[1] 苏瀛鹏[1] 徐艳丽[1] 胡雨来[1] 

机构地区：[1]西北师范大学化学化工学院,兰州730070

出　　处：《有机化学》2014年第5期948-955,共8页Chinese Journal of Organic Chemistry

基　　金：国家自然科学基金(No.21062016)资助项目~~

摘　　要：报道了锡粉促进下,以四氢呋喃(THF)为溶剂,在室温条件下,通过醛、芳甲酰肼和烯丙基溴"一锅法"反应,合成高烯丙基酰肼化合物的方法.该方法具有条件温和,不使用任何催化剂,操作简单,产率高等优点.An one-pot reaction was developed for the synthesis of homoallylhydrazides by treating aldehydes, aryl acylhydmzines and allyl bromide with tin powder at room temperature in tetrahydrofuran. The reaction proceeded smoothly without using any catalyst under mild conditions to give the corresponding products in high yields.

关 键 词：一锅法 锡粉 醛 酰肼 高烯丙基酰肼 

分 类 号：O623.752[理学—有机化学]