5,10,15,20-四(对-癸酰氧基苯基)卟啉过渡金属配合物的合成与表征  

Synthesis of Tetra(4-p-decanoyloxyphenyl) Porphyrin Complexes

作　　者：柳巍[1] 陶建中[2] 师同顺[3] 

机构地区：[1]第四军医大学化学教研室 [2]河南职业技术师范学院 [3]吉林大学化学系,长春130023

出　　处：《应用化学》2001年第3期228-230,共3页Chinese Journal of Applied Chemistry

基　　金：国家自然科学基金资助课题 !(5 9783 0 0 1)

摘　　要：Six complexes of tetra(4 p decanoyloxyphenyl)porphyrin(TDPPH 2) with Mn(Ⅲ), Fe(Ⅲ), Co(Ⅱ), Ni(Ⅱ), Cu(Ⅱ) and Zn (Ⅱ) have been synthesized in a mixed solvents of CH 2Cl 2 and DMF. The compounds were characterized by elemental analysis, UV Vis, FTIR photoacoustic spectrometry, 1H NMR and molar conductance measurements. The optical textures of the isotropic liquid crystals of TDPPH 2 and TDPPZn on cooling were observed by polarized light microscope.Six complexes of tetra(4 p decanoyloxyphenyl)porphyrin(TDPPH 2) with Mn(Ⅲ), Fe(Ⅲ), Co(Ⅱ), Ni(Ⅱ), Cu(Ⅱ) and Zn (Ⅱ) have been synthesized in a mixed solvents of CH 2Cl 2 and DMF. The compounds were characterized by elemental analysis, UV Vis, FTIR photoacoustic spectrometry, 1H NMR and molar conductance measurements. The optical textures of the isotropic liquid crystals of TDPPH 2 and TDPPZn on cooling were observed by polarized light microscope.

关 键 词：卟啉 过渡金属配合物 液晶 合成 结构表征 

分 类 号：O641.4[理学—物理化学]