响应面法优化中温固化酚醛树脂的制备  

Optimization of preparation of mid-temperature curing phenol-formaldehyde resin by response surface methodology

作　　者：黄剑峰[1,2] 陈奶荣[1] 林巧佳[1] 饶久平[1] 曾钦志[1] 

机构地区：[1]福建农林大学材料工程学院,福建福州350002 [2]中国建材检验认证集团厦门宏业有限公司,福建厦门361000

出　　处：《南京林业大学学报（自然科学版）》2014年第3期179-183,共5页Journal of Nanjing Forestry University：Natural Sciences Edition

基　　金：国家自然科学基金项目(30972311);福建省科技厅产学研重大专项基金项目(2010N5001);福建省林业厅科学基金资助项目(闽林科201103-2)

摘　　要：以尿素、间苯二酚为改性剂，在碱性条件下制备中温固化酚醛树脂。利用Design-Expert软件建立数学模型，以胶合强度为响应值，优化酚醛树脂的原料配比。结果表明，中温固化酚醛树脂原料的最佳配比为：甲醛与苯酚摩尔比为2？32，氢氧化钠与苯酚摩尔比0？56，尿素加量为苯酚质量的20？03％，间苯二酚加量为苯酚质量的9？98％。在此条件下制备的酚醛树脂可以在105～115℃下固化。Urea and resorcinol were used as modifiers to prepare mid-temperature curing phenol-formaldehyde resin （PF） in alkaline condition, and the response surface methodology was used to optimize the effects of raw materials ratio on bond-ing strength. The optimal raw materials ratio of PF were determined as follows：molar ratios of formaldehyde and alkali to phenol were 2？32 and 0？56, respectively;and the mass of urea and resorcinol to phenol were 20.03%and 9？98%, respec-tively. Under these raw materials ratio, the curing temperature of the PF was in the range of 105-115℃.

关 键 词：尿素 间苯二酚 酚醛树脂 响应面法 

分 类 号：TQ323.1[化学工程—合成树脂塑料工业]