WSH-2型催化剂在环氧丙烷/苯乙烯装置废气处理中的工业应用  

Industrial Application of WSH-2 Catalyst in Treatment of PO/SM Waste Gas

作　　者：王新[1] 陈玉香[1] 王学海[1] 刘忠生[1] 

机构地区：[1]中国石化抚顺石油化工研究院,辽宁抚顺113001

出　　处：《化工环保》2014年第3期240-244,共5页Environmental Protection of Chemical Industry

基　　金：中国石化科技部"十条龙"攻关课题项目(308027)

摘　　要：介绍了WSH-2型催化剂在环氧丙烷（PO），苯乙烯（SM）装置废气处理中的应用。工业化装置的运行结果表明，在废气处理量86000Nm3／h、设定反应器进口温度250~300℃、设定进口非甲烷总烃（YMHC）质量浓度1000—2200mg／m3的条件下，无论单系列还是双系列运转，采用WSH-2型催化剂均可对废气进行有效处理。处理后气体中的NMHC、苯、甲苯、乙醛、SM等的含量均符合GB16297--1996《大气污染物综合排放标准》和GB14554--1993《恶臭污染物排放标准》中的相关规定。NMHC去除率达到92．9％以上，装置运行稳定。按照目前的废气排放工况推算，预计催化剂的使用寿命可达5a。The industrial application of WSH-2 catalyst in the treatment of waste gas from propylene oxide/ styrene monomer（PO/SM） device is introduced. The application results show that PO/SM waste gas can be effectively treated by WSH-2 catalyst in both simple and double operation system under the conditions of treatment capacity 86 000 Nm3/h, set inlet temperature 250-300℃ and inlet total non-methane hydrocarbon（NMHC） mass concentration 1 000-2 200 mg/m3. The contents ofNMHC, benzene, toluene, acetaldehyde, SM in the treated gas can meet the national emission standards of GB 16297-1996 and GB 14554-1993. The removal rate of NMHC is over 92.9%, and the device works steadily. According to the existing waste gas emission, the service life of the catalyst is expected for 5 years.

关 键 词：环氧丙烷 苯乙烯 废气处理 催化氧化 WSH-2型催化剂 

分 类 号：X51[环境科学与工程—环境工程]