Synthesis of well-defined functional crystals by high temperature gas-phase reactions  

作　　者：Hai-Bo Jiang Lin-Feng Pan Peng-Fei Liu Wen-Qi Fang Hua-Gui Yang 

机构地区：[1]Key Laboratory for Ultrafine Materials of Ministry of Education,School of Materials Science and Engineering,East China University of Science and Technology [2]Centre for Clean Environment and Energy,Griffith University,Gold Coast Campus,Brisbane,QLD 4222,Australia

出　　处：《Chinese Science Bulletin》2014年第18期2135-2143,共9页

基　　金：supported by the National Natural Science Foundation of China (91022023,21076076);the Scientific Research Foundation for the Returned Overseas Chinese Scholars,State Education Ministry (SRF for ROCS,SEM);Programme for Professor of Special Appointment (Eastern Scholar) at Shanghai Institutions of Higher Learning;Major Basic Research Programme of Science and Technology Commission of Shanghai Municipality (10JC1403200);Shanghai Municipal Natural Science Foundation (12ZR1407500)

摘　　要：Over the past decades,there have been many synthesis methods on producing well-defined crystals,due to their enormous application potentials in industrial field.Among them,high temperature gas-phase reactions(HTGR)approach may be one of the most promising processes for fabrication of well-defined crystals with controllable structure,size,shape,and composition.This review is focused on the recent progresses in synthesizing well-defined crystalline TiO2dominated with,respectively,{001}facets and{105}facets,one-dimensional ZnO and SnO2nanorods/nanowires,MoS2nanosheets as well as GaP,InP,and GaAs nanowires via HTGR approach.Although these research works were currently carried out on experimental scale,it is worth to note that the industrial importance of this HTGR approach for design and fabrication of well-defined crystals in the future owing to its advantages of continuous and scalable production with controlled dimensions and low cost.Over the past decades, there have been many synthesis methods on producing well-defined crystals, due to their enormous application potentials in industrial field. Among them, high temperature gas-phase reactions （HTGR） approach may be one of the most promising processes for fabrication of well-defined crystals with controllable structure, size, shape, and composition. This review is focused on the recent progresses in synthesizing well-defined crystalline TiO2 dominated with, respectively, {001 } facets and { 105 } facets, one-dimensional ZnO and SnO2 nanorods/nanowires, MoS2 nanosheets as well as GaP, InP, and GaAs nanowires via HTGR approach. Although these research works were currently carried out on experimental scale, it is worth to note that the industrial importance of this HTGR approach for design and fabri- cation of well-defined crystals in the future owing to its advantages of continuous and scalable production with controlled dimensions and low cost.

关 键 词：高温气冷堆 气相反应 多晶体 定义 反应合成 SNO2纳米棒 纳米二硫化钼 工业领域 

分 类 号：O78[理学—晶体学]