Tb(P_2Mo_(17)O_(61))_2/PAMAM纳米复合膜的制备及荧光性质研究  

The study of preparation and fluorescent property of nanosized composite film constructed from Tb(P_2Mo_(17)O_(61))_2 and PAMAM

作　　者：张晓凤[1] 何晓蕾[1] 黄晓灵[1] 黄秋锋[1] 林深[1] 

机构地区：[1]福建师范大学化学与化工学院,福州350007

出　　处：《功能材料》2014年第6期45-50,共6页Journal of Functional Materials

基　　金：国家自然科学基金资助项目(21171037;21103022);福建省自然科学基金资助项目(2011J0101;21103022);福建省教育厅资助项目(JA11063;JA13085;JB13009)

摘　　要：利用层接层自组装法技术,制备了"稀土多金属氧酸盐/聚酰胺-胺树形分子"无机/有机纳米荧光薄膜[Tb(P2Mo17O61)2/PAMAM]n,利用紫外-可见光谱(UV-Vis)、X射线光电子能谱(XPS)、原子力显微镜(AFM)、荧光光谱对所制备的薄膜进行了组成、结构和性能的表征。研究结果表明,无机和有机组分通过静电作用成膜,复合膜的增长是线性均一、层层增长的过程,复合膜表面是由粒径较为均匀的球状粒子分布而成。与固体Tb(P2Mo17O61)2相比,复合膜的荧光激发光谱出现了一宽的配体-金属电荷跃迁峰,发射光谱不但体现了稀土元素Tb3+的特征发射,且Tb3+劈裂出一新的发射峰,新峰的出现是由于Tb3+所处的晶体场的对称性减弱引起的。The inorganic/organic luminescent nanocomposite film based on polyoxometalate anion Th （I2Mo17 O61 ）2]17 and polyamidoamine （PAMAM） dendrimer was prepared hy layer -by-layer technology. The components swuctures and properties of the film were characterized by UV Vis, XPS, AFM and fluorescence spectroscopy. The results showed that elec＇wostatic interaction exists between inorganic and organic compo nents. The growth processes of the assembled film were quantitative and highly reproducible from layer tolay er. The surface was smooth and dispersed with uniform spherical particles. Compared with the solid Tb （P2Mo17O61）2,the excitation specwum of Tb（P2Mo17O61）2/PAMAM film showed a board ligand to metal charge transfer band. The film exhibited the characteristic emission peaks of Tb：＋, In addition, anewpeakap peared in the emission spectra, which may result from the lower symmetry of Tb＋ crystalline field in the film.

关 键 词：层层自组装 多金属氧酸盐 聚酰胺-胺 多层复合膜 荧光 

分 类 号：O644[理学—物理化学]