硫醇-烯/炔点击化学制备有机/无机杂化材料  

Synthesis of Organic/Inorganic Hybrid Materials via Thiol-Ene/Yne Click Chemistry

作　　者：杨正龙[1] 徐晓黎[1] 赵宇馨[1] 

机构地区：[1]同济大学材料科学与工程学院先进土木工程材料教育部重点实验室,上海200092

出　　处：《化学进展》2014年第6期996-1004,共9页Progress in Chemistry

基　　金：国家高技术研究发展计划(863)项目(No.2012AA030303);中央高校基本科研业务费专项资金(同济大学)(No.0500219145);同济大学大型仪器设备开放测试基金项目(No.2012014);上海市科委基础研究重点项目(No.12JC1408600)资助~~

摘　　要：有机/无机杂化材料因其独特、优异的结构和性能已经成为目前材料领域的研究热点,硫醇-烯/炔点击化学是近年发展起来的一类新型点击化学,以其反应条件温和、速率快、产率高、产物容易分离以及高度选择性等优点受到国内外研究者的广泛关注。本文综述了近年来硫醇-烯/炔点击化学制备有机/无机杂化材料的研究进展,重点介绍了利用硫醇-烯/炔点击化学制备硅类、碳类、金属及金属氧化物类有机/无机杂化材料,并归纳了这些有机/无机杂化材料在生物医用、环境保护、光电材料等方面的应用,最后展望了硫醇-烯/炔点击化学制备有机/无机杂化材料未来的发展方向。During last several decades, organic/inorganic hybrid materials have been used widely in many fields due to their excellent structure and performance. Thiol-ene/yne click chemistry, a new type of click chemistry, is of great interest because of its mild reaction conditions, fast reaction rate, high yield, easy post-treatment and high selectivity for the obtained products. Therefore, synthesis of high-performance organic/inorganic hybrid materials via thiol-ene/yne click chemistry is one of the hot topics of novel material research. In this review, the recent research progress of organic/inorganic hybrid materials synthesized by thiol-ene/yne click chemistry is discussed. Synthesis of silicon-, carbon-, metal- and metal oxide-based organic/inorganic hybrid materials via thiol-ene/yne click chemistry is highlighted. In addition, the applications of these hybrid materials in the fields of biomedical materials, environment protection and photoelectric materials are summarized. Finally, the development trend and future prospects of organic/inorganic hybrid materials synthesized by thiol-ene/yne click chemistry are presented.

关 键 词：有机 无机杂化材料 点击化学 硫醇-烯 炔 生物医用 环境保护 光电材料 

分 类 号：O631.5[理学—高分子化学] O633.3[理学—化学]