烯唑醇锌盐配合物的合成与结构表征  

The syntheses and characterizations for zinic-diniconazole complexes

作　　者：高金胜[1] 马东升[1] 马忠国[1] 陈国荣[1] 侯艳君[1] 叶玲[2] 

机构地区：[1]黑龙江大学化学化工学院,黑龙江哈尔滨150080 [2]吉林大学超分子结构与谱学重点实验室,吉林长春130023

出　　处：《分子科学学报》2001年第1期17-22,共6页Journal of Molecular Science

基　　金：黑龙江省自然科学基金资助项目! (B971 1 );吉林大学超分子结构与谱学重点开放实验室课题资助项目

摘　　要：合成了 2个新配合物ZnL4 Cl2 和ZnL4 (H2 O) 2 ·(NO3 ) 2 (L =烯唑醇 ) ,通过元素分析、IR光谱和核磁共振谱表征了配合物的结构 .X射线单晶衍射结构分析表明 :ZnL4 Cl2 晶体属三斜晶系 ,空间群P墿,晶胞参数 :a =0 882 80(7)nm ,b =1 370 94(11)nm ,c=1.5 182 9(13)nm ,α =91.0 72 (10 )°,β =98 5 97(10 )°,γ =10 6 .779(8)° ,V =1.735 8(2 )nm3 ,Z =1;ZnL4 (H2 O) 2 ·(NO3 ) 2 晶体属单斜晶系 ,空间群Cc,晶胞参数 :a =1.5 2 430 (13)nm ,b =1.5 85 4(2 )nm ,c =3.336 1(4 )nm ,α =90 0 0 0° ,β =10 0 .2 2 7(8)° ,γ =90 0 0 0°,V =7 934 (2 )nm3 ,ZNew complexes ZnL 4Cl 2 and ZnL 4(H 2O) 2·(NO 3) 2(L=diniconazole) were synthesized and characterized by element analysis, IR and 1 HNMR spectra. the structures of the two complexes were determined by X-ray diffusion. ZnL 4Cl 2 belongs to triclinic, P ī space group, crystal cell parameter: a =0.882 80(7) nm, b =1.370 94(11) nm, c =1.518 29(13) nm, α=91.072(10)°,β=98.597(10) °,γ=106.779(8) °, V =1.735 8(2) nm 3, Z =1. ZnL 4(H 2O) 2·(NO 3) 2 belongs to monoclinic, Cc space group, crystal cell parameters: a =1.524 30(13) nm, b =1.585 4(2) nm, c =3.336 1(4) nm, α=90.000°,β=100.227(8)°,γ=90.000°, V =7 934(2) nm 3, Z =1.

关 键 词：烯唑醇 锌配合物 合成 晶体结构 杀菌剂 

分 类 号：TQ455.4[化学工程—农药化工]