环氧琥珀酸及其衍生物研究进展  

Research Progress of Epoxysuccinic Acid and Derivative

作　　者：王宝辉[1] 钱慧娟[2] 侯志峰[2] 高清河[2] 

机构地区：[1]东北石油大学化学化工学院,黑龙江大庆163318 [2]大庆师范学院黑龙江省普通高等学校油田应用化学重点实验室,黑龙江大庆163712

出　　处：《大庆师范学院学报》2014年第3期32-37,共6页Journal of Daqing Normal University

基　　金：黑龙江省普通高校石油与天然气化工重点实验室资助项目(HXHG2012-01)

摘　　要：环氧琥珀酸是一种重要的化工中间体,由于分子结构中含有醚基使其衍生物具有多种功能,日益受到人们的重视。本文首先从烯烃环氧化反应机理、环氧琥珀酸合成方法和含量测定方法等方面综述了环氧琥珀酸单体合成规律的研究现状。同时重点阐述了环氧琥珀酸的化学反应,包括水解反应、均聚反应和共聚反应,并对一些应用前景较好的环氧琥珀酸类衍生物做了详细介绍。最后,对环氧琥珀酸的研究方向提出了建议。Epoxysuccinic acid was a kind of important chemical intermediate and its derivative were multi-func-tional as the result of the ether bond in molecular structure which was drawing increasing attention.Based on ep-oxidation reaction mechanism of olefins, synthetic method of epoxysuccinic acid,determination method of content and other aspects, research status on synthesis regularity of epoxysuccinic acid were reviewed in this paper.On the other hand, chemical reaction of epoxysuccinic acid including hydrolysis reaction, homopolymerization , co -polymerization were elaborated and some derivative with great prospect in industrial application were described in detail.Finally, suggestions for the further research of epoxysuccinic acid were proposed.

关 键 词：环氧琥珀酸 环氧化反应 均聚反应 共聚反应 机理 

分 类 号：TQ316.3[化学工程—高聚物工业]