功能化茂铁巯基共轭分子的合成与电化学性质  

Synthesis and electrochemical properties of functionalized substituted thiol-derivatized-ferrocene conjugated molecules

作　　者：鄢剑锋 王薇 柯成锋 林达强 袁耀锋 

机构地区：[1]椭州大学化学系,福州350108

出　　处：《科学通报》2014年第17期1582-1590,共9页Chinese Science Bulletin

基　　金：国家自然科学基金(21172036);教育部高等学校博士学科点专项科研基金(博导类,20113514110002)资助

摘　　要：共轭有机低聚物由于其多样性、易修饰性等优良性质已被广泛应用于分子导线的设计与合成.单分子的组装与光电性能是共轭有机分子研究的重点与难点.含寡聚苯撑乙炔(OPE)构筑块的单分子自组装膜由于其良好的光电性能,已被大量地用于共轭分子导线的电子传递性能研究.二茂铁基团的引入,大大扩展了单分子自组装膜(SAMs)的电化学性质和应用范围.本文重点介绍了近十几年来含巯基(或乙酰巯基)茂铁共轭分子体系的结构与光电性质,并对其未来的发展进行了展望.Because of its diversity, easy modification and other unique properties, conjugated organic oligomers have been widely used in the design and synthesis of molecular wires. The photoelectric property and self-assembly of single-moleculars are the two critical points in the research of conjugated organic molecules. The self-assembled monolayer film containing oligo-polyphenylene ethynylene （OPE） building blocks, due to its good optical properties, has been widely used to study the electron transfer properties of conjugated molecular wires. The introduction of ferrocene group greatly expands the electrochemical property and application of self-assembled monolayers. This review emphasizes the research progresses on the synthesis and photoelectric properties of functionalized substituted thiol-derivatized-ferrocene conjugated molecules in the last decade.

关 键 词：二茂铁 巯基 自组装膜 电化学性质 分子导线 

分 类 号：O621.3[理学—有机化学]