植酸自组装膜对Q235钢在氯化钠溶液中的缓蚀作用  

Phytic acid as a corrosion inhibitor for 235 steel in NaCl solution

作　　者：王凤平[1] 胡隋军 唐丽娜[1] 

机构地区：[1]辽宁师范大学化学化工学院,辽宁大连116029

出　　处：《辽宁师范大学学报（自然科学版）》2014年第2期233-237,共5页Journal of Liaoning Normal University:Natural Science Edition

基　　金：辽宁省高校创新团队项目(LT20100055)

摘　　要：从植物中提取的植酸作金属缓蚀剂对环境保护具有重要意义.采用失重法、扫描电子显微镜和X射线能谱研究了植酸对Q235钢在NaCl溶液中的缓蚀行为以及影响因素.失重实验结果表明,不同pH值植酸对Q235钢的缓蚀效果明显不同,在酸性条件下植酸加速Q235钢的腐蚀,在中性及碱性条件下,植酸对Q235钢的腐蚀具有明显的抑制作用.中性或碱性条件下,NaCl溶液中植酸对Q235钢缓蚀效率随植酸浓度的增加而增加,植酸浓度达0.5%以上时,缓蚀效率高达90%以上.扫描电镜结果表明,植酸处理后的Q235钢表面生成膜在不同pH下明显不同,碱性条件下的生成膜明显好于酸性条件下的生成膜.The corrosion inhibition of phytic acid on Q235 steel in NaCl solution was investigated by weight loss technique ,scanning electronic microscopy and the energy spectrum of X rays .The results show that inhibition efficiency of phytic acid on Q 235 steel in NaCl solution is obviously different at different pH .Phytic acid can accelerate the corrosion rate of Q 235 steel under acidic condition .But under neutral and alkaline condition ,phytic acid has excellent corrosion inhibition for 235steel in NaCl solution .Nevertheless ,the corrosion inhibition efficiency of phytic acid for Q235 steel in NaCl solu-tion increases with increasing phytic acid concentration under neutral and alkaline condition .If the concentration of phytic acid is 0 .5% ,the inhibition efficiency is more than 90% .

关 键 词：植酸 Q235钢 缓蚀行为 影响因素 

分 类 号：O636[理学—高分子化学]