STRUCTURE OF NOVEL DICOPPER(Ⅱ) COMPLEX Cu_2 (oxpn) (NCS)_2 (H_2O)(oxpn=N,N'-bis(3-aminopropyl) oxamido)  

作　　者：姚心侃 廖代正 等 

机构地区：[1]CentralLaboratory,NankaiUniversity,Tianjin300071 [2]D

出　　处：《Chinese Journal of Structural Chemistry》1991年第2期143-146,共4页结构化学（英文）

摘　　要：C10H10Cu2N6O4S2,Mr = 475. 41,monoclinic,space group P2/c,a = 8. 531 (2),b= 6. 870(1) ,c= 14. 463(2) A ,β=93. 84 (2), V= 845. 7 A3,Z=2,D = 1. 866 g·cm-3,μ=27. 799cm-1,F(000) = 484,R=0. 071. The molecules possesse basically a planar structure ,with the two aquamolecules displaced 2. 75 A to opposite sides of this plane and being at the apexpositions of the square pyramidal coordination of the two Cu atoms, respectively, the two carbonyls of the oxamide show the "trans-form".C10H10Cu2N6O4S2,Mr = 475. 41,monoclinic,space group P2/c,a = 8. 531 (2),b= 6. 870(1) ,c= 14. 463(2) A ,β=93. 84 (2), V= 845. 7 A3,Z=2,D = 1. 866 g·cm-3,μ=27. 799cm-1,F(000) = 484,R=0. 071. The molecules possesse basically a planar structure ,with the two aquamolecules displaced 2. 75 A to opposite sides of this plane and being at the apexpositions of the square pyramidal coordination of the two Cu atoms, respectively, the two carbonyls of the oxamide show the "trans-form".

分 类 号：O614.121[理学—无机化学] O76[理学—化学]