反相液相色谱三元流动相组成保留值方程的考察  

Investigation on the Fundamental Elution for the Relationship between the Composition of Ternary Mobile Phase and Chromatographic Retention in Reversed-Phase Liquid Chromatography

作　　者：陈农[1,2] 张玉奎[1,2] 董礼孚 包绵生[1,2] 卢佩章 

机构地区：[1]中国科学院大连化学物理研究所 [2]中国大连色谱技术研究开发中心

出　　处：《色谱》1989年第6期321-324,共4页Chinese Journal of Chromatography

摘　　要：本文在反相三元冲洗剂条件下,验证了保留值方程Ink=a+b_1Inc_(B1)+b_2Inc_(B2)+c_1c_(B1)+c_2c_(B2),详细讨论了其中的参数,并提出了计算这些参数的方法。In this paper, equation lnk'=a + b1lnCB1+ b2lnCB2 + C1CB1 + C2CB2 which describes the relationship between the composition of the ternary mobile phase and chromatographic retention is proven in RPLC. The detailed investigation for the parameters in this equation has been carried out. The method for calculating the parameters is described.

关 键 词：反相液相色谱 三元流动相 保留值方程 三元冲洗剂 

分 类 号：O657.72[理学—分析化学]