含砜基和二氮杂萘酮结构的聚酰亚胺无规共聚物的合成与性能  

SYNTHSIS AND PROPERTIES OF POLYIMIDE RANDOM COPOLYMERS CONTAINING SULFONE AND 4-(4-HYDROXYLBENYL) -2,3-PHTHALAZINYL-1-ONE

作　　者：王锦艳[1] 蹇锡高[1] 肖树德[1] 张守海[1] 

机构地区：[1]大连理工大学化工学院高分子材料系,大连116012

出　　处：《高分子学报》2001年第2期277-280,共4页Acta Polymerica Sinica

摘　　要：A novel unsymmetrical dianhydride containing 4\|(4\|hydroxylphenyl)\|2,3\|phthalazin\|1\|one was synthesized in order to improve the solubility of aromatic polyimides according to the principle of designing new monomers.This article reported a series of polyimide random copolymers derived from 4,4′ diamino diphenyl sulfone (DAPS),4,4′ oxyl dianiline (ODA) and the new dianhydride\|2 (3,4 dicarboxyl phenyl) 4 (3′,4′ dicarboxyl phenyl oxyl) phenyl 2,3 phthalazine 1 one dianhydride (DAH4) by“one step”solution polycondensation in m cresol with catalystic amount of isoquinoline at 200℃.Some properties of the copolymers were investigated by DSC,TG and mechanical analysis.The result shows that the η inh of copolymers is between 0 64 to 0 71 dL/g in m cresol at 25℃,and the T g of the copolymers are higher than that of pure poliymides containing 4,4′ oxyl dianiline (polymer 5).The relationship between T g and mole percent of DAPS is not obvious.Degradation temperature for 5% weight loss ( T d5 ) of the copolymers occurs all above 470℃ in air.The mechanical properties of the copolymers are lower owing to introducing sulfone groups into polymer’s backbone.In sharp contrast,the copolymers have good solubility and can be easily soluble in 1,1,2,2 tetrachloroethane(TCE), N,N dimethylacetamide(DMAc), N methyl 2 pyrrolidinone (NMP), m cresol and pyridine.Furthermore,the copolymers have better solubility in dimethyl sulfoxide (DMSO) and chloroform than the polyimide derived from DAH4 and ODA.A novel unsymmetrical dianhydride containing 4-(4-hydroxylphenyl)-2,3-phthalazin-1-one was synthesized in order to improve the solubility of aromatic polyimides according to the principle of designing new monomers. This article reported a series of polyimide random copolymers derived from 4,4'-diamino diphenyl sulfone (DAPS),4,4'-oxyl dianiline (ODA) and the new dianhydride-2-(3,4-dicarboxyl-phenyl)4- (3', 4'-dicarboxyl-phenyl-oxyl)-phenyl-2,3-phthalazine-1-one dianhydride (DAH4) by 'one-step' solution polycondensation in m-cresol with catalystic amount of isoquinoline at 200 degreesC. Some properties of the copolymers were investigated by DSC, TG and mechanical analysis. The result shows that the eta (inh) Of copolymers is be tween 0.64 to 0.71 dL/g in m-cresol at 25 degreesC and the T-g of the copolymers are higher than that of pure poliymides containing 4,4'-oxyl dianiline (polymer 5). The relationship between T-g and mole percent of DAPS is not obvious. Degradation temperature for 5% weight loss (T-d5) of the copolymers occurs all above 470 degreesC in air. The mechanical properties of the copolymers are lower owing to introducing sulfone groups into polymer's backbone. In sharp contrast, the copolymers have good solubility and can be easily soluble in 1,1,2,2-tetrachloroethane (TCE), N,N-dimethylacetamide (DMAc), N-methyl-2-pyrrolidinone (NMP), m-cresol and pyridine. Furthermore, the copolymers have better solubility in dimethyl sulfoxide (DMSO) and chloroform than the polyimide derived from DAH4 and ODA.

关 键 词：聚酰亚胺 4 4′-二氨基二苯醚 4 4′-二氨基二苯砜 “一步法”溶液聚合 无共聚物 合成 性能 

分 类 号：O633[理学—高分子化学]