不同方法制备的Mo/HZSM-5催化剂上甲烷的芳构化反应  

Methane Dehydro-Aromatization over Mo/HZSM-5 Catalyst Prepared by Different Methods

作　　者：舒玉瑛[1] 田丙伦[1] 马丁[1] 包信和[1] 徐奕德[1] 

机构地区：[1]中国科学院大连化学物理研究所催化基础国家重点实验室,大连116023

出　　处：《催化学报》2001年第2期109-112,共4页

基　　金：国家重点基础研究发展规划项目! (G19990 2 2 40 6)

摘　　要：采用机械混合、机械混合后焙烧和机械混合后微波处理等方法制备Mo/HZSM 5催化剂 ,并对催化剂上甲烷芳构化反应性能进行了考察 .结果表明 ,与浸渍法相比 ,用机械混合法、固相反应法和微波法制备的催化剂 ,在保持甲烷转化率不变的前提下 ,能明显提高芳烃选择性并减少积炭的生成 ;不同方法制备的Mo/HZSM 5催化剂上Mo物种的落位不同 ,机械混合法、固相反应法和微波法使Mo物种较多地落位于分子筛外表面 .结合反应结果可以得出 ,落位于分子筛外表面的Mo物种对甲烷芳构化反应更为有利 ,而且明显减少积炭的生成 .Mo/HZSM-5 is a typical catalyst for methane dehydro-aromatization in the absence of oxygen. The catalyst was prepared with impregnation method in previous studies. In this paper, mechanical mixing, solid reaction and microwave methods were used for Mo/HZSM-5 preparation. In addition, the catalytic performance of the catalyst for methane dehydro-aromatization was investigated. Compared with impregnated Mo/HZSM-5 sample, the catalyst samples prepared with mechanical mixing, solid reaction and microwave methods show higher selectivity for aromatics and lower selectivity for coke. BET, XRD and NH3TPD experimental results exhibited that the location of Mo species is heavily dependent on the preparation method. It is suggested that the Mo species located on the external surface of the zeolite is more efficient for methane dehydro-aromatization, and at the same time suppresses the coke formation.

关 键 词：钼基催化剂 HZSM-5分子筛 制备方法 表征 甲烷 芳构化 积炭 

分 类 号：O643[理学—物理化学]