铽多元配合物的合成及其性质研究  

Synthesis and Properties of Terbium Multiligand Complexes

作　　者：汪联辉[1] 王文[1] 章文贡[1] 

机构地区：[1]福建师范大学高分子研究所,福建福州350007

出　　处：《中国稀土学报》2001年第1期91-94,共4页Journal of the Chinese Society of Rare Earths

基　　金：福建省自然科学基金!资助项目 (B9810 0 0 8)

摘　　要：通过铽金属醇盐与丙烯酸、β二酮配体反应 ,合成了 4种具有聚合活性的含铽配合物单体 ,通过元素分析红外光谱、紫外光谱 ,确定了它们的组成和结构。热分析表明 ,这些铽配合物单体没有熔点 ,起始分解温度在 190～ 2 0 0℃之间。在溶液及粉末状态下研究了这些含铽多元配合物的荧光性质。在紫外光激发下 ,它们均能发射铽离子的特征荧光。溶剂的极性和配体的三线态能级会影响它们荧光强度 ;粉末状态下 ,这些铽多元络合物的荧光单色性较好。Four kinds of terbium containing monomers were synthesized by the reaction of Tb isopropyl oxide with acrylic acid and β diketones. The composition and structure of these monomers were confirmed by FT IR,UV spectroscopy and elemental analysis. DTA and TG analyses revealed that the decomposition temperature of these monomers, which is at the range of 190～200 ℃. The fluorescence properties of these monomers were studied. Under the excitation of UV light, these monomers exhibit characteristic luminescence of trebium ion, and the fluorescent intensity is affected by the polarity of solvent and triplet state of ligand. In solid state, the monochromatic index of luminescence is enhanced.

关 键 词：铽多元配合物 荧光性质 合成 丙烯酸 Β二酮 稀土发光材料 

分 类 号：O614.341[理学—无机化学] O482.31[理学—化学]