氟两相催化反应的进展  

Fluorous Biphasic Catalysis

作　　者：廖永卫[1] 陈卫平[1] 

机构地区：[1]第二军医大学化学教研室,上海200433

出　　处：《有机化学》2001年第3期181-190,共10页Chinese Journal of Organic Chemistry

摘　　要：对氟两相催化反应作一介绍。氟两相体系是一种新的相分离和固定化技术 ,全氟溶剂与大多数有机溶剂不互溶 ,而在催化剂分子中引入适当数量、大小和形状的氟尾能使之优先溶于全氟溶剂 。Fluorous biphase system represents a new phase-separation and immobilization technique. Perfluorinated solvents have limited miscibility with most of organic solvents. Combined with the fact that compounds functionalized with fluorous ponytails of appropriate number, size, and shape often dissolve preferentially in pefluorinated solvents allows the easy recovery and recycling of fluorous catalysts. This review focuses on fluorous biphasic catalysis.

关 键 词：氟两相体系 全氟溶剂 相行为 氟代催化剂 氟两相催化反应 有机催化合成 

分 类 号：O643.3[理学—物理化学]