非离子水溶性膦配体的合成及其应用进展  

Review on the Synthesis of Nonionic Water-Soluble Phosphines and Their Application in Biphasic Catalysis

作　　者：刘晓忠[1] 王艳华[1] 缪强[1] 金子林[1] 

机构地区：[1]大连理工大学精细化工国家重点实验室,大连116012

出　　处：《有机化学》2001年第3期191-199,共9页Chinese Journal of Organic Chemistry

基　　金：国家自然科学基金 (No .2 990 60 0 1;2 9792 0 74);大连理工大学精细化工国家重点实验室基金(KF980 8)资助项目

摘　　要：按非离子水溶性膦配体的发展特点 ,就羟基取代膦配体、天然碳水化合物为母体的膦配体、聚醚基取代的膦配体、具手性中心的膦配体、高分子负载型膦配体、温控相转移膦配体。The paper categorized nonionic water-soluble phosphines reported in the literature into hydroxy-subsituted phosphines, natural carbohydrate-supported phosphines, polyether-substitued phosphines, chiral phoshines,polymer-supported phosphines, thermoregulated phase-transfer catalytic phosphines and cyclodextrin-modified ligands, and reviewed on the synthesis of the phosphines and their application in aqueous biphasic catalysis.

关 键 词：非离子水溶性膦配体 丙相催化 过渡金属配合物 合成 催化剂 

分 类 号：O641.4[理学—物理化学]