Crystal Structure of 〔Aqua(oxalato)(1,10-phenanthroline)(H_2O)〕copper(Ⅱ) Monohydrate  

作　　者：苏成勇 李代珂 等 

机构地区：[1]InstituteofPhysicalChemistry,SchoolofChemistryandC [2]InstituteofPhysicalChemistry,

出　　处：《Chinese Journal of Structural Chemistry》1998年第2期147-150,共4页结构化学（英文）

摘　　要：The title compound FCu (C2O4) (phen ) H2O)] H2O (phen=1, 10-phenanthroline) crystallizes in monoclinic system, space group P21/n with a = 8. 453 1639 observed reflections. The Cu(Ⅱ) atom is coordinated bytwo N atoms of phen, two O atoms of oxalate and one O atom of water, and in square-pyramidal environment. The molecules of the structure are joined to each other in thecrystal lattice by hydrogen bonds to yield a one-dimensional chain structure.The title compound FCu (C2O4) (phen ) H2O)] H2O (phen=1, 10-phenanthroline) crystallizes in monoclinic system, space group P21/n with a = 8. 453 1639 observed reflections. The Cu(Ⅱ) atom is coordinated bytwo N atoms of phen, two O atoms of oxalate and one O atom of water, and in square-pyramidal environment. The molecules of the structure are joined to each other in thecrystal lattice by hydrogen bonds to yield a one-dimensional chain structure.

关 键 词：crystal structure OXALATE PHENANTHROLINE copper complex 

分 类 号：O614.121[理学—无机化学] O76[理学—化学]