SYNTHESES OF TUNGSTEN COMPLEXES WITH o-MERCAP-TOPHENOL.CRYSTAL STRUCTURE OF (Ph_4P)[WO(OMe)(mp)_2]  

作　　者：胡永韩 陈学太 等 

机构地区：[1]StateKeyLaboratoryofstructuralChemistry,FujianInst [2]StateKeyLaboratoryofstructura

出　　处：《Chinese Journal of Structural Chemistry》1993年第5期401-404,共4页结构化学（英文）

摘　　要：Reaction of WCl6, mpH2 o-mercaptophenol) and MeONa in the presence of Ph4PBr gave complexes (Ph4P)[W(mp)3] (1) and (Ph4P) CWO(OMe) (mp)2] (2). Crystal data complex (2), C37H31O4PS2W, Mr = 818. 61, monoclinic, space group P2/a, a=26. 555(3), b=9. 634(1), c=13. 523(7) A. β=94. 68 (2)°, V=3448. 1 A3. A=1. 58 g/cm3, Z = 4. λ(MoKα)=0. 71073 A , μ= 36. 2 cm-1, F(000) = 1624, T=296K, final R(Rw) = 0. 068(0. 070) for 3929 observed reflections. The WO4S2 core is arranged in a distorted octahedral geometry.

关 键 词：Synthesis Crystal Structure Tungsten Complex 

分 类 号：O614.613[理学—无机化学] O76[理学—化学]