The Crystal Structure of 1, 4, 7, 10- Tetraazacyclododecane Hydrate Triperchlorate  

作　　者：KONG De-Yuan XIE Yu-Yuan ZHU Qin  XIE Yu-Li(Shanghai Institute of Material Medica, the Chinese Academy of Sciences,No. 294, Taiyuan Road, Shanghai 200031, China)HUANG Xiao-Ying(Fujian Institute of Research on the Structure of Matter,the Chinese Academy 

出　　处：《Chinese Journal of Structural Chemistry》1998年第4期293-295,共3页结构化学（英文）

摘　　要：The title complex [(C8H23N4)3+ (ClO4)3-]. H2O was crystallized intriclinic system, P1 space group with unite cell parameters: a= 8. 386(2), b= 10. 558(2), c=11. 865(3) A, a= 77. 75(2)’ β= 72. 65(2),γ= 74. 77(2)°, V= 957. 3(4)A3, Z= 2, Dc= 1. 706 g/cm3, M,=491. 66, F(000) = 512, μ(MoKa) =5. 49cm-1,=0. 71069 (graphite- monochromated), T = 296K. The title complex is composed ofone [C8H23N4]3+ cation, three ClO4 ions and one crystal water molecule. The final Rand Rw values are 0. 058 and 0. 068 respectively.

关 键 词：crystal structure tetraazacyclododecane PERCHLORATE HYDRATE 

分 类 号：O626[理学—有机化学] O76[理学—化学]