CRYSTAL STRUCTURE OF A SILVER COMPLEX Ag(PPh_3)_2(S_2P-(OCH_3)_2)  

作　　者：朱永宝 王金枝 等 

机构地区：[1]FuzhouLaboratoryofStructurealChemistryandFujianIns [2]FuzhouLaboratoryofStructureal

出　　处：《Chinese Journal of Structural Chemistry》1993年第4期289-292,共4页结构化学（英文）

摘　　要：The crystal structure of the title silver complex has been determined by the single crystal X-ray diffraction method.The white plate crystal is tri-clinic.space group P1 with a=12.289(1),b=13.330(2),c=14.846(1)A.α=59.78(1),β=70.33(1),γ=64.01(1)°,V=1867.9A3,Z=2,Dc=1.404 g/ cm3,Mr=789.6,F(000)=808,MoKa radiation,μ(MoKa)=7.891 cm-1,final R=0.049 and Rw=0.051 for 5753 observed reflections.The silver(I)is surrounded by two P and two S atoms in a distorted tetrahedral coordination.The crystal structure of the title silver complex has been determined by the single crystal X-ray diffraction method.The white plate crystal is tri-clinic.space group P1 with a=12.289(1),b=13.330(2),c=14.846(1)A.α=59.78(1),β=70.33(1),γ=64.01(1)°,V=1867.9A3,Z=2,Dc=1.404 g/ cm3,Mr=789.6,F(000)=808,MoKa radiation,μ(MoKa)=7.891 cm-1,final R=0.049 and Rw=0.051 for 5753 observed reflections.The silver(I)is surrounded by two P and two S atoms in a distorted tetrahedral coordination.

关 键 词：晶体结构 银配合物 三苯基膦 二甲氧基二硫代膦配位体 

分 类 号：O614.122[理学—无机化学] O76[理学—化学]