羟基特戊酸新戊二醇单酯合成研究  

Synthesis of Hydroxypivalate

作　　者：罗志强[1] 刘键[1] 申东升[1] 张仕华[1] 姜忠民[1] 

机构地区：[1]湘潭大学化学化工学院

出　　处：《化工时刊》2001年第3期31-33,共3页Chemical Industry Times

摘　　要：以异丁醛和甲醛为原料,经羟醛缩合制得羟基特戊醛,二元催化剂氢氧化钙和二氯化铝催化进行Tischenko缩合,高效率合成出酯基热稳定、抗水解、抗氧化、分子结构柔性、非常适合于高性能抗冲击韧性树脂和优质润滑剂制造的羟基特戊二醇单酯。Hydroxypivalyl hydroxypivalate (HPHP), which is structurally flexible with an ester group that is thermal stable and highly resistant to oxidation and hydrolysis, has been synthesized efficiently by Tischenko condensation of hydroxypivalaldehyde ( HPA) which was prepared by adol condensation of isobutyraldehyde and formaldehyde. The compound is very useful as a diol for polymers and lubricants. A binary catalyst consisting of calcium hydroxide and aluminum chloride was employed to promote Tischenko condensation.

关 键 词：羟基特戊酸新戊二醇单脂 羟基特戊醛 Tischenko缩合 合成 

分 类 号：O623.624[理学—有机化学]