氢化丁苯橡胶的性能与表征  

Characterization and properties of hydrogenated styrene - butadiene rubber

作　　者：李晓东[1] 谢洪泉[2] 

机构地区：[1]湖北省化学研究所,湖北武汉430074 [2]华中理工大学化学系,湖北武汉430074

出　　处：《合成橡胶工业》2001年第2期87-90,共4页China Synthetic Rubber Industry

基　　金：中国石油合成橡胶技术开发中心资助!项目

摘　　要：用ＩＲ，ＤＳＣ，ＴＥＭ表征了由丁苯胶乳氢化制备的氢化丁苯橡胶（ＨＳＢＲ）的微观结构及结晶状态，并测定了ＨＳＢＲ老化前后的力学性能。结果表明，ＨＳＢＲ在较高氢化度下形成了较多的结晶聚乙烯链段，具有较好的力学性能、优异的耐热老化性及耐候稳定性；ＨＳＢＲ的氢化度愈高，结晶度愈大，物理机械性能愈优异，可作为优良的耐老化型热塑性弹性体。Microstructure and crystalline state of hydrogenated styrene-butadiene rubber (HSBR) from hydrogenation of SBR latex were characterized by IR, DSC and TEM. Mechanical properties of the HSBR before and after thermal aging were also studied. The results showed that in the HSBR with higher hydrogenation degree crystalline polyethylene segments were formed in the chains. HSBR possessed good mechanical properties, excellent thermal aging resistance and weathering aging resistance due to the crystalline segments and saturation of double bonds. The more the hydrogenation degree, the higher the crystallinity, and the better the properties of the HSBR were. The product could be used as anti-aging thermoplastic elastomer.

关 键 词：丁苯胶乳 加氢 氢化丁苯橡胶 热塑性弹性体 微观结构 老化性能 表征 

分 类 号：TQ333[化学工程—橡胶工业]