无机填料对PET结晶行为、力学性能和流变性能的影响  

EFFECT OF NUCLEATING AGENTS ON CRYSTALLIZATION, MECHANICAL AND RHEOLOGICAL BEHAVIOR OF POLY(ETHYLENE TEREPHTHALATE)

作　　者：雷呜[1] 于中振[1] 欧玉春[1] 杨桂生[1] 

机构地区：[1]中国科学院化学研究所分子科学中心

出　　处：《高分子材料科学与工程》2001年第2期105-108,共4页Polymer Materials Science & Engineering

摘　　要：利用差示扫描量热仪 ( DSC)研究了碳酸钙、滑石粉等无机填料对 PET等温和非等温结晶行为的影响 ,并与适于 PET用的有机钠盐类成核剂 NA作了对照。结果表明 ,滑石粉比碳酸钙更有利于 PET结晶速率的提高 ,当滑石粉用量为 5% (质量 ) ,其对 PET等温结晶速率的贡献接近 1% (质量 )有机成核剂 NA的贡献。而且 ,滑石粉的加入明显提高了 PET拉伸强度和弯曲模量 ,而成核剂 NA的使用虽然有助于 PET弯曲模量的提高 ,却使 PET拉伸强度、弯曲强度 ,特别是冲击强度减小。这可能是由于碳酸钙和滑石粉对 PET是异相成核 ,对 PET分子量影响不太大 ;而成核剂 NA却是通过与 PET反应生成PET钠盐而促进结晶的 ,其副作用是导致 PET分子降解 ,表现为 PET/Effects of inorganic fillers on isothermal and non isothermal crystallization kinetics of polyethylene terephthalate(PET) were studied by using DSC in comparison with an organic uncleating agent(NA). The results indicate that Talc has a better nucleating effect on PET crystallization rate than CaCO 3, 5 mass% Talc has a similar effect on PET isothermal crystallizatio rate to 1 mass% nucleating agent NA. Moreover, the presence of Talc can improve the tensile strength and flexural modulus of PET. Although nucleating agent NA increase the flexural modulus of PET, it decreases the tensile strength and flexural strength, especially Izod impact strength of PET. The reasons are probably that CaCO 3 and Talc have heterogeneous nucleation effects on the PET crystallization and little influence on the molecular weight of PET; however, the nucleating agent NA reacts with PET, causes the degradation of PET molecules and decreases the viscosity of PET/NA system.

关 键 词：聚对苯二甲苯乙二醇酯 成核剂 结晶行为 力学性能 无机填料 PET 

分 类 号：TQ323.41[化学工程—合成树脂塑料工业] O633.14[理学—高分子化学]