用蒽和对苯二甲醛合成的COPNA树脂的研究  

A Study on the Properties of COPNA Resins Synthesed From Anthracene (Ant) and Terephthalic Aldehyde (TPA)

作　　者：李彦[1] 何力[1] 陈开勋[2] 

机构地区：[1]西安石油学院化学工程系,陕西西安710065 [2]西北大学化学系,陕西西安710069

出　　处：《西安石油学院学报（自然科学版）》2001年第3期36-38,共3页Journal of Xi'an Petroleum Institute（Natural Science Edition)

摘　　要：以蒽为单体 ,对苯二甲醛为交联剂 ,在对甲基苯磺酸催化下 ,进行合成 COPNA树脂实验研究 .经反复实验 ,筛选出最佳对甲基苯磺酸 ( PTS)质量分数为 5% ,最佳反应温度为 1 90℃ .通过对COPNA树脂的红外光谱和核磁共振波谱的分析 ,证明蒽 -对苯二甲醛在酸催化下 ,发生亲电取代反应 .并对树脂的耐热性能进行了评价 .结果表明 :原料摩尔比为 1 .0的 COPNA树脂在 40 0℃开始明显失重 ,最大失重速率时的加热温度为 52 9.1℃ ,失重速率为 2 .63× 1 0 -2 min-1;80 0℃时炭化收率为 58.COPNA resins were synthesed from anthracene and terephthalic aldehyde under the catalysis of p toluensulfonic acid(PTS). Accoroling to the synthesis experiments, it is found that the optimum reaction temperature is 190℃,and that the optimum mass fraction of PTS is 5%. The analysis of IR and NMR of the resins show that electrophilic substatution occured between anthracene and terephthalic aldelyde under acid catalysis. The experimental results also show that the thermogravimetry of the COPNA resin with 1.0 mole ratio of TPA to Ant begins obviously at 400℃,the maximum thermogravimetric rate occured at 529.1℃, the rate is 2.63%/min, and carbonorphism yield is 58.7% at 800℃. The heat resistance of the COPNA resin was measured.

关 键 词：蒽 对苯二甲醛 热固型耐高温树脂 缩合多环多核芳香烃树脂 

分 类 号：TQ326.9[化学工程—合成树脂塑料工业]