锰(Ⅱ)呋喃甲醛Schiff碱催化苯乙烯环氧化的研究  

THE CATALYTIC PERFORMANCE OF Mn FURALDEHYDE SCHIFF BASE COMPLEXES IN STYRENE EPOXIDATION

作　　者：南光明[1] 孙斌[2] 胡家元[2] 陈骏如[2] 李贤均[2] 

机构地区：[1]新疆伊犁师范学院,新疆伊犁835000 [2]四川大学化学学院,四川成都610064

出　　处：《化学研究与应用》2001年第2期182-183,173,共3页Chemical Research and Application

摘　　要：Mn complexes with N,N′ bis(furaldehyde)1,2 phenylenediamine(1)、N,N′ bis(furaldehyde) ethylenediamine(2),N,N′ bis(furaldehyde)1,2 diaminopropane(3),N,N′ bis(furaldehyde)1,3 diamino propane(4), and N,N′ bis(furaldehyde) diethylenetriamin(5) were used as catalysts in styrene epoxidation.The influences of different ligand,pH,axial ligand and reaction tiom on reactions were discussed.Mn complexes with N,N′ bis(furaldehyde)1,2 phenylenediamine(1)、N,N′ bis(furaldehyde) ethylenediamine(2),N,N′ bis(furaldehyde)1,2 diaminopropane(3),N,N′ bis(furaldehyde)1,3 diamino propane(4), and N,N′ bis(furaldehyde) diethylenetriamin(5) were used as catalysts in styrene epoxidation.The influences of different ligand,pH,axial ligand and reaction tiom on reactions were discussed.

关 键 词：锰配合物 苯乙烯 环氧化 催化反应 呋喃甲醛 西佛碱 

分 类 号：O625.12[理学—有机化学] O643.36[理学—化学]