催化褪色光度法测定痕量镁(Ⅱ)的研究  

STUDY ON THE DETERMINATION OF TRACE MAGNESIUM(Ⅱ) BY CATALYTIC KINETIC DISCOLORING SPECTROPHOTOMETRY

作　　者：彭在姜[1] 陈国树[1] 郭俊杰[1] 

机构地区：[1]南昌大学化学系,江西南昌330047

出　　处：《南昌大学学报（理科版）》2001年第1期81-86,共6页Journal of Nanchang University(Natural Science)

摘　　要：在NH3·H2 O介质中 ,以Mg(Ⅱ )作活化剂 ,Mn(Ⅱ )催化H2 O2 氧化二甲苯胺兰Ⅱ褪色为指示反应 ,建立了痕量镁 (Ⅱ )的动力学分析方法。本方法的测定范围为 0 - 0 .80 μgMg2 +/2 5mL ,检测限为 3.8× 10 - 11g/mLMg2 +,应用于锌合金中痕量镁 (Ⅱ )的测定 。It has been found that Mn(Ⅱ) can catalyze the discoloration of xylidyl blue Ⅱ by hydrogen peroxidate in ammonia solution,while Mg(Ⅱ) acts as a promoter.The kinetic conditions of this reaction have been studied,a new method for the determination of trace magnesium(Ⅱ) is proposed.Its linear range is 0-0.80 μg/25 mL Mg(Ⅱ) and the detection limit is 3.8×10 -11 g/mL Mg(Ⅱ).It has been applied satisfactorily to the determination of trace Mg(Ⅱ) in zinc alloy.

关 键 词：催化褪色光度法 锌合金 镁 含量测定 动力学分析方法 褪色反应 

分 类 号：TG146.13[一般工业技术—材料科学与工程] TG115.335[金属学及工艺—金属材料]