双杂原子Ti-V-ZSM-5分子筛的合成与表征  

Synthesis and characterization of zeolite Ti-V ZSM-5 containing double heteroatoms

作　　者：霍丽华[1] 赵经贵 马淑杰[2] 

机构地区：[1]黑龙江大学化学化工学院,黑龙江哈尔滨150080 [2]吉林大学化学系,吉林长春130023

出　　处：《黑龙江大学自然科学学报》2001年第1期82-85,共4页Journal of Natural Science of Heilongjiang University

基　　金：黑龙江省自然科学基金资助课题!(9732)

摘　　要：在无碱性离子存在下，以硅溶胶、硫酸钛、硫酸氧钒为原料，分别采用四两基溴化胺（ＴＰＡＢｒ）、１，６－己二胺（１，６－ＨＤＡ）及正丁胺（Ｒ－ＮＨ２）模板剂，首次合成了双杂原子Ｔｉ－Ｖ－ＺＳＭ－５分子筛，并对产物的物性与结构进行了表征。The synthesis of zeolite Ti-V-ZSM-5 containing double heteroatoms with silica sol as Si sources, titanium sulfate and vandium oxisulfate as the starting materials and tetrapropyl ammonium bromide(TPABr), 1, 6 -dihexamine(1, 6-HDA) and n -butyladrine as the templates, respectively was investigated for the first time in the absence of alkali-metal ions. Some physical and chemical properties and the structure of the product were characterized by using XRD, SEM, TG-DTA, IR, UV-Vis spectra.

关 键 词：双杂原子 Ti-V-ZSM-5分子筛 水热合成 结构表征 硅溶胶 硫酸钛 硫酸氧钒 

分 类 号：O643.36[理学—物理化学] S[理学—化学]