催化氢甲酰化反应的研究进展  

Progresses in the Research of Catalytic Hydroformylation Reaction

作　　者：鲜启鸣[1] 袁强[1] 龚炜丽[1] 

机构地区：[1]江苏省生产力促进中心,江苏南京210042

出　　处：《江苏化工》2001年第2期21-24,共4页Jiangsu Chemical Industry

摘　　要：回顾烯烃氢甲酰化 6 0年来取得的成就 ,简要地概述了氢甲酰化反应催化体系的发展过程。通过对各个阶段的催化剂性能比较 ,分析了水溶性铑膦复合物催化剂成为低碳烯烃氢甲酰化首选催化剂的主要原因。阐述了现阶段氢甲酰化催化体系的研究进展和发展趋势。指出新的水 -有机两相催化及多相催化技术将是今后的努力方向。In this article the achievements of alkene's hudroformylation in around 60 years are reviewed, and the development course of catalysis system for this reaction is simply summarized. Through the comparison of the properties of catalyst in each period, the reason why the water-soluble rhodium-phosphine complexes have been the first catalysts for low carbon alikeness is analyzed. Research progresses and development trend of hydroformylation catalysts system, especially for higher olefin hydroformylation are sum up, energetic orientation for new water-organic two phase's catalysts and heterogeneous catalysts is suggested.

关 键 词：烯烃 氢甲酰化 均相催化 多相催化 

分 类 号：TQ221.2[化学工程—有机化工] TQ203.2