Ni[(C_4H_9O)_2PS_2]_2与氮碱加合反应的研究  

A Study on the Adductive Reaction of Ni[(C_4H_9O)_2PS_2]_2 with Nitrogen Bases

作　　者：贺敏强[1] 程晓农[2] 朱多林[1] 俞运鹏[1] 

机构地区：[1]镇江师范专科学校化学系,江苏镇江212001 [2]江苏理工大学材料科学与工程学院,江苏镇江212013

出　　处：《江苏理工大学学报（自然科学版）》2001年第3期50-53,共4页Journal of Jiangsu University of Science and Technology(Natural Science)

基　　金：江苏省教育厅自然科学基金资助项目! (99KJB15 0 0 0 6 )

摘　　要：用光谱法研究了Ni[(C4H9O) 2 PS2 ]2 与咪唑、邻菲咯啉在乙醇溶液中的加合反应 ,测定了反应的平衡常数lgβn 及加合分子数n ,在 32℃时 ,与咪唑反应lgK1 =2 .85± 0 .0 7,lgβ2 =5.69± 0 .0 9;与邻菲咯啉反应lgβ2 =7.68± 0 .1 1 比较了咪唑与吡啶类化合物的平衡常数值的大小 ,得到了平衡常数值不仅与氮碱的 pKa值有关 。Adductive reaction of Ni[(C 4H 9O) 2PS 2] 2 with Imidazole and 1,10 Phenanthroline in Ethanol has been studied spectrophotometrically. The equilibrium constants with Imidazole and 1,10 phenanthroline are found to be lg K 1=2.85±0.07, lg β 2=5.69±0.09 and lg β 2=7.68±0.11 respectively. The equilibrium constants of Imidazole have been compared with the equilibrium constants of pyridine and some of its derivatives.The results have demonstrated that equilibrium constants are concerned with not only pKa of nitrogen bases but also the space effect of nitrogen bases.

关 键 词：二硫代磷酸酯镍 加合反应 平衡常数 UV-VIS光谱 

分 类 号：O641.813[理学—物理化学]