气相色谱高温液晶固定液的合成和性能——Ⅴ.具液晶侧链的聚丙烯酸酯类  

Syntheses and Properties of High-Temperature Liquid Crystals as Stationary Phase in Gas Chromatography Ⅴ. Polyacrylates with Liquid Crystalline Side-Chain

作　　者：华曦[1] 张文娟[1] 孙科夫 李国镇[1] 林栋 

机构地区：[1]华东化工学院应用化学研究所 [2]上海天原化工厂

出　　处：《华东化工学院学报》1991年第6期700-709,共10页

摘　　要：合成了聚[对-(丙烯酰氧基乙氧基苯甲酰氧基)苯甲酸对-甲(乙)氧基苯酚酯]。其液晶相温度范围为86.0～280.0℃。将其用作气相色谱固定液,成功地分离了19种稠环芳烃的混合标样以及焦化重油。The polyacrylates, poly [p-methoxylphenyl or p-ethoxylphenyl p-(acryloyloxylethoxylbenzoyloxyl) benzpate] were synthesized and characterized. Their liquid crystal temperature range is from 86.0～280.0℃. When used as stationary phase in gas chromatography, the liquid crystal polymers have satisfactory results in the separation of the mixture containing nineteen polynuclear aromatic compounds and the heavy oil from coal tar.

关 键 词：液晶 固定液 气相色谱 苯二酚 

分 类 号：O753.2[理学—晶体学]